Gain
The short version
How hot the signal is going into something.
Gain sets the input level — how strongly a sound hits your preamp, plugin or amp. Push it hard and the character changes: it can get thicker, then distorted.
Why you'd careGain is at the start of the chain and affects tone. Volume is at the end and only affects how loud you hear it. Turning up gain can change the sound; turning up volume shouldn't.
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